OCTANE RATING QUESTION FOR CHEMISTRY WIZARDS | FerrariChat

OCTANE RATING QUESTION FOR CHEMISTRY WIZARDS

Discussion in 'Technical Q&A' started by GCalo, Nov 3, 2006.

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  1. GCalo

    GCalo F1 Veteran

    Sep 15, 2004
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    I had contact with an ECU software writer (yes I know but be open minded) who stated that:

    "US 92 fuel compares to European 97 Ron. I think if you could get 92 and add a little booster to it you could well be where we need to be."

    The reference here is to supposed 97 octane fuel available in Europe and its extreme positive effects upon ECU upgrades.

    Can any actual petrochemical wizards here comment on this supposed comparison as well as what the "booster" is he's mentioning (and, Mike, that's not a booster seat!).

    On the way to Concorso I stopped in San Juan Baptista at a Union 76 station that had 92 octane at the pump. Whew. What an effect on performance! It was as if someone was pushing, and the car was loaded with clothes, etc.

    So, are the octane comparisions he made accurate?
     
  2. JCR

    JCR F1 World Champ
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    Mar 14, 2005
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    In the U.S. we use (RON + MON)/2, usually listed on the pump as (R+M)/2
    Other countries only use RON.
    RON = Research Octane Number
    MON = Motor Octane Number
    RON vs. MON = different testing procedures, RON gives a higher number.

    Our 93 is comparable to their 97. There is no point in adding additional octane if the engine doesn't need it.
     
  3. GCalo

    GCalo F1 Veteran

    Sep 15, 2004
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    Thanks for the valuable info.

    You guys in Texas can get 93 cause George Bush is there.

    However the highest I have seen in Calif is the 92 I purchased in August, but 91 is the norm.

    So where do you think the 91 stands with relation to the euro 97?
     
  4. judge4re

    judge4re F1 World Champ

    Apr 26, 2003
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    Which 91? California 91, winter 91 or regular 91?
     
  5. f355spider

    f355spider F1 World Champ
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    May 29, 2001
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    The typical method for converting Europe's "RON" octane rating to the North American "AKI" octane rating is to multiply the RON rating by .95 to get the AKI. So 97 RON would be 92.15 AKI. The other quick and dirty method is to subtract four units from the RON rating....

    So 91 AKI divided by .95 equals 95.8 RON.

    There are various octane booster additives available at auto supply stores. You can try them to see if it makes a difference...I believe the Ferrari manual states 91 AKI is the fuel requirement. Higher shouldn't make much difference. Less octane than 91 could mean less performance, as the knock sensor will retard the ignition if it sense pinging from the lower octane fuel.

    There are chip programming companies out there, and they often times will optimize their chip to your car, taking in to account the fuel available to you. I have seen one company that makes chips for Ferraris optimized at 91 AKI and also for 93 AKI.
     
  6. GCalo

    GCalo F1 Veteran

    Sep 15, 2004
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    Any recommendations as to what those boosters would be?

    My guess is that per gallon they will be higher than the cost of gas.

    I can tell you that 92 made a very noticeable difference!
     
  7. JCR

    JCR F1 World Champ
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    The 91 octane is to punish all the flakey libs that live in Cali. No, not really....

    Unocal had the patent on California Reformulated Gasoline (RFG). All the other companies decided they would just sell lower octane gasoline instead of paying Unocal the 5 cents a gallon royalty. Now that Chevron bought Unocal and the patent effectively died as a condition imposed by the FTC to approve the merger, you might think the octane rating would creep back up. But since octane costs money, and Californians are conditioned to use 91, it will probably stay the same unless one of the refiners decides for marketing reasons to offer 93 forcing the other to follow. See why your gasoline is different below.

    http://www.exxon.com/USA-English/Files/US%20Gasoline%20Map%20100102.pdf
     
  8. GCalo

    GCalo F1 Veteran

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    I can't bring that link up. It must have run out of "gas"!
     
  9. JCR

    JCR F1 World Champ
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  10. Simba

    Simba Formula Junior

    Oct 24, 2006
    779
    New York
    The little octane booster bottles you find at auto parts stores are a complete waste of time. Most of them are comprised almost entirely of an aromatic hydrocarbon like Toluene or Xylene, which have r+m/2 octane ratings of 114 and around 117, respectively.

    So, the average can of octane booster is around a pint. If your fuel tank holds, say, 15 gallons of 93 octane pump, and you dump a pint of 117ish octane booster into it, you'll have a net result of around 93.16 octane. Woo, raised it one and a half points, and basically accomplished nothing save made SuckerCo a bit richer as you just dropped $5-10 bucks on 1/8th a gallon of high octane go juice (by comparison, 100 octane race fuel is around $5/gallon).

    So, if you fill your tank with 10 gallons of 93 pump, and then dump in 5 gallons of Sunoco GT100, for example, you've got ~95.4 octane. A significant increase.

    For a naturally aspirated engine running less than 12:1 compression, 93 octane pump should be plenty to keep you out of detonation, even while flogging it on a track.

    If you're unfortunate enough to live in California, and are forced to use the swill they call gas over there, I'd definitely mix race fuel with it if you're playing with timing maps.

    If you're feeling an increase in power after using higher octane fuel than you normally do, it's because the computer has been pulling timing to prevent detonation/pre-ignition. Better gas, more timing advance, more Horsey Music.

    There is a limit, however, when adding octane will no longer provide any benefit, and simply increase cost.
     
  11. GCalo

    GCalo F1 Veteran

    Sep 15, 2004
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    I don't necessarily want to add octane. I want to take advantage of what's available, and I believe the analysis of additives.

    I think the term "additive" refers to the added profit for its maker! You are correct.

    The 92 I purchased was the first time I had seen such high octane at the pump.

    I would estimate 100 octane would be about $8.00/gallon? Not worth mixing.

    Thanks to all for the great chemistry lessons. I see if more Union 76 stations in the area have 92.
     
  12. Simba

    Simba Formula Junior

    Oct 24, 2006
    779
    New York
    Not sure what it is in Cali. Around here it goes for ~$5/gallon.
     
  13. GCalo

    GCalo F1 Veteran

    Sep 15, 2004
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    Everything in California is more expensive.

    You guys have cheap gas and high property taxes.

    We have high gas and low property taxes!
     
  14. sammyb

    sammyb Formula 3

    Jun 23, 2006
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    And here in WA we have high gas tax (actually, the highest in the country)
    high sales tax
    medium property tax
    no income tax

    Race gas will probably be about the same cost across the country. What usually makes the fuel cost increase for standard regular/89/premium is the special blends required for each market. Since race fuel is exempt from emissions law, because it is supposed to be for track use only, it generally stays pretty flat. ($5/gallon as previously mentioned.)
     
  15. Birdman

    Birdman F1 Veteran

    Jun 20, 2003
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    Quit your complaining! We in the People's Republic of Taxachusetts have high sales tax, high income tax, high property tax, expensive fuel, AND Ted Kennedy.

    Birdman
     
  16. GCalo

    GCalo F1 Veteran

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    And that's exactly why I moved from there to Calif over 30 years ago.

    Can't afford to run a business in that state with the taxes and the weather!

    Ted Kennedy had nothing to do with it for me!
     
  17. GCalo

    GCalo F1 Veteran

    Sep 15, 2004
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    Interestingly I ran into Spidey on Sunday. He told me that there is a new gas station in Sunol off Andrade that sells 100 octane from a pump for around $5.80/gallon.

    He uses it for his TT Porsche that has had the ECU remapped.

    So, it's available in the area, but I don't see the value to mix it as was discussed here. It's just good to know it's available.
     
  18. lusso64

    lusso64 Formula 3

    Apr 12, 2004
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    Maybe do the calcs to create a tank of 95 and see how it runs. It may end up being well worthwhile for those fun occasions.... Then again, it might be a waste of $ and at least you can tell us this before we waste our hard earned :)

    Do we really have cheap property tax in CA? I'm paying 8K a year to have Antonio do anything BUT be the mayor.....
     
  19. smg2

    smg2 F1 World Champ
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    whenever i'm in newport i'll use 100 octane only. usually costs me just over $110 per tank. but man the difference! esp now since i've added boost. runs smoother and the exhaust smells alot cleaner. too bad it'll only last me a day of "cruising" around ;)
     
  20. lusso64

    lusso64 Formula 3

    Apr 12, 2004
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    Not intending to hijack this thread anymore than it has already been, but while on the subject of gas, I have just done a search on lead substitutes and so forth. The Lusso has had ongoing issues for years with crap in the gas and we are finally going all out to purge everything and get the gunk out. Once completed, the question is.... do we add "stuff" to the gas or not?

    I have read here that since the 250 has Alumin(i)um heads, they have valve seat inserts so are not susceptible to lack of lead problems. I have also read of one 330 owner who has used regular unleaded without additives for 100,000+ miles with no issues. Then of course there are the other statements - "only run without additive if you want to spend 25K having the heads redone".

    So. What's the consensus? If an additive, which one? Most lead substitute additives claim to boost octane also. I suspect that with the low CR that Ferraris have had (until 348s) that regular unleaded will suffice in terms of octane.

    Thanks...
     
  21. GCalo

    GCalo F1 Veteran

    Sep 15, 2004
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    My suspicion is that if you do not have a remapped ECU you are wasting money on 100 octane.

    What value is 95+ octane if the ECU can't recognize it and the engine can't benefit from it.

    I know that 92 was quite noticeably different in performance but would I realize the same from even higher octane?

    I am tending to doubt it.

    Anyone know for sure?

    I can understand what Scott said, but he has a screaming machine. But the thought of $100.00 for a day's gas gives me gas!
     
  22. Simba

    Simba Formula Junior

    Oct 24, 2006
    779
    New York
    The ECU doesn't know what you have in the tank. What it knows is when you run into detonation, and as a result, when to pull timing so it is reduced/eliminated. If you're noticing significant performance gains when you crank up the octane, the fuel you were running before you did is not adequate.

    As a general rule of thumb, baring any odd circumstances (endurance racing, extremely hot climates, oddly shaped combustion chambers prone to hot spotting, etc), you won't see any benefit to running greater than 94-95 octane in a naturally aspirated engine with a compression ratio below 12:1, assuming a stock EFI computer with un-messed-with timing and fuel maps.

    When it comes to forced induction applications, or NA engines running huge timing, the sky's the limit. I've seen engines run into pre-ignition on C16.
     
  23. GCalo

    GCalo F1 Veteran

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    Our standard premium here in NorCal is 91.

    Having found the 92 at Union76 was a surprise.

    So, maybe our 91 isn't and maybe that 92 was actually 93!
     
  24. smg2

    smg2 F1 World Champ
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    correct, i also have another oddity - i'm still running the CIS so i have no feedback or ignition interplay. the electromotive also has no way of knowing if i'm detonating either so it takes a good ear and big balls to get pushy with the timing ;) at 10~12psi and 9:1 compression the higher the octane the more HP and less chance of 'BOOM' so $100 tanks are cheap insurance when i want to run hard.

    mmmmmmm C16 is very tempting! when i update the electromotive i'll run a tank. BTW i have no cats or O2 on the early CIS so lead isn't an issue.
     
  25. SRT Mike

    SRT Mike Two Time F1 World Champ

    Oct 31, 2003
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    The irony of higher octane gasoline is that it has less energy than lower octane. That's right - there is theoretically more performance using a lower octane, PROVIDED you are not suffering detonation.

    GCalo, I understand what you are saying about a "noticeable performance improvement" when you used 92, but unless you were suffering severe detonation, it really should not be possible to feel a difference. If you were detonating badly on 91, something else would be wrong with the car.

    Having said that, what I would do is get something like a g-tech or some other performance computer and do side-by-side tests with the various gas and test your results. I suspect they may be much closer than you imagine.

    on a turbocharged/supercharged car, higher octane is a godsend, because it lets you bump the boost (or lets the ECU bump the boost, sometimes). On a NA car, higher octane should have no effect - actually a net negative effect, as long as you weren't detonating on the lower octane.

    You may have had a tank of bad 91 gas if you noticed a big improvement with 92 over 91.
     

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